Independent Publications

Mechanistic Interrogation of Photochemical Nickel-Catalyzed Tetrahydrofuran Arylation Leveraging Enantioinduction Data

McManus, B. D.; Hung, L. C.; Taylor, O. R.; Nguyen, P. Q.; Cedeño, A. L.; Arriola, K.; Bradley, R. D.; Saucedo, P. J.; Hannan, R. J.; Luna, Y. A.; Farias, P. and Bahamonde, A. J. Am. Chem. Soc. 2024 accepted.

Pre-print: https://chemrxiv.org/engage/chemrxiv/article-details/66837f78c9c6a5c07afedba2 

Leveraging the Redox Promiscuity of Nickel To Catalyze C–N Coupling Reactions

Taylor, O. R.; Saucedo, P. J.; Bahamonde, A.  J. Org. Chem. 2024, in press

Invited perspective for Next-Generation Cross-Coupling Chemistry special issue.

Mechanistic Evidence of a Ni(0/II/III) Cycle for Nickel Photoredox Amide Arylation

Bradley, R. D.; McManus, B. D.; Yam J. G.; Carta, V.; Bahamonde, A.  Angew. Chem. Int. Ed. 2023, 202310753

Hot paper and in the top in accessed papers from ACIE in September 2023

Mild Amide N-Arylation Enabled by Nickel-Photoredox Catalysis

Bradley, R. D.; Bahamonde, A. Org. Lett. 2022, 24, 7134–7139

Highlighted in Chemistry views

Mild Sustainable Amide Alkylation Protocol Enables a Broad Orthogonal Scope

Hibbard, J. P.; Yam, J. G.; Alsalek, E. B.; Bahamonde, A. J. Org. Chem. 2022, 87, 12036–12040

In the top 5 in downloaded papers from JOC in August 2022

Mechanistically guided survey of enantioselective palladium-catalyzed alkene functionalization

Bahamonde, A. Trends Chem. 2021, 10, 863-876

Postdoctoral Publications

Predicting relative efficiency of amide bond formation using multivariate linear regression

Haas, B. C.; Goetz, A. E.; Bahamonde, A.; McWilliams, J. C.; Sigman, M. S. PNAS 2022, 119, e2118451119.

Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines

Bahamonde, A.; Al Rifaie, B.; Martín-Heras, V.; Allen, J. R.; Sigman, M. S. J. Am. Chem. Soc. 2019, 141, 8708

Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction

Allen, J. R.; Bahamonde, A.; Furukawa, Y.; Sigman, M. S. J. Am. Chem. Soc. 2019, 141, 8670

Doctoral Publications

Studies on the Enantioselective Iminium Ion Trapping of Radicals Triggered by an Electron-Relay Mechanism

Bahamonde, A.; John J. Murphy, J. J.; Savarese, M.; Brémond, E.; Cavalli, A.; Melchiorre, P. J. Am. Chem. Soc. 2017, 139, 4559

X-Ray characterization of an EDA complex which drives the photochemical alkylation of indoles

Kandukuri, S.; Bahamonde, A.; Chatterjee, I.; Jurberg, I. D.; Escudero-Adán, E. C.; Melchiorre, P. Angew. Chem., Int. Ed. 2015, 54, 1485

Enantioselective direct α-alkylation of cyclic ketones by means of photo-organocatalysis

Arceo, E.;† Bahamonde, A.;† Bergonzini, G.; Melchiorre, P. Chem. Sci. 2014, 5, 2438